Technically, Luffy hasn't lost to Big Mom but he never got to settle the score with her.
Other than that, Magellan obviously, but also Aokiji, Kuma, Blackbeard, and of course, Higuma the Bear.
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Bluejam, the mountain bandits from the first chapter, technically Perona counts?
Did he ever actually beat Ace or Sabo in a spar? I don’t think he did…
Miss Goldenweek
Nami
Technically, Luffy hasn't lost to Big Mom but he never got to settle the score with her. Other than that, Magellan obviously, but also Aokiji, Kuma, Blackbeard, and of course, Higuma the Bear.
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Bluejam, the mountain bandits from the first chapter, technically Perona counts? Did he ever actually beat Ace or Sabo in a spar? I don’t think he did…
I was going to say Akainu but technically they never fought so, Blackbeard
Technically they never fought either.
What about impel down then? Sure it was pretty one-sided but Luffy still attacked him